Chelate of isopropyl tris (dioctyl pyrophosphate acyloxy) ethylene titanate and triethanolamine HY-311W

Corresponding foreign brands: American Kenrich Petrochemicals Inc. KR-138s or KR-238s

Main chemical components:

Physical and chemical properties:

This product is a dark yellow or dark orange-red viscous liquid with a flash point of 160℃, density ρ (20℃): 1.101, refractive index n 20℃ 1.471, and decomposition temperature of 210℃. Soluble in isopropyl alcohol, xylene, toluene, insoluble in water. This product is a non-toxic and non-corrosive liquid. The oral poisoning amount of white mice is LD 50 10g/kg (reference value: salt LD 50 3.8g/kg)

Application areas:

Plastic products, rubber products, adhesives, FRP products, paints, inks, ointments, magnetic materials, waterproof materials, composite flame retardants, etc.

Application object:

1. Matrix resin: PE, PP, PS, PC, AS, ABS, PVC, SBS, polyester, polyether, polyurethane, polyamide, polycarbonate and other thermoplastic, thermosetting resins and other elastomers.
2. Inorganic fillers: CaCO₃, MgCO₃, BaSO₄, CaSO₄, MgO, Al(OH)₃, talc powder, mica powder, lithopone powder, titanium dioxide, wollastonite powder, pyrophyllite powder, sepiolite powder, Carbon black, clay, bentonite, aluminum smelting red mud, iron red, chrome yellow, titanium cyanine blue, antimony trioxide, ammonium polyphosphate, zinc metaborate, etc.

Product Features:

1. This product is a chelating titanate coupling agent, suitable for processing high humidity filler. Such as precipitated white carbon black, clay, talc, silicate, carbon black, glass fiber, etc.
2. This product can significantly increase the dispersibility, anti-settling and storage stability of pigments such as carbon black, iron red, medium chrome yellow, and titanium cyanine blue in organic base materials, shorten the grinding time and the number of channels, improve Paint film adhesion, appearance, corrosion resistance, enhanced adhesion and catalytic curing and other functions (see "Coating Dispersion Coupling Agent" for details).
3. Chelating titanate coupling agent has better viscosity reducing effect than monoalkoxy type, its addition ratio is better at 1.0-1.2%, it will continue to increase, the effect is not obvious.
4. This product has obvious effect in rubber products, such as increasing tensile strength, tear strength, elongation and aging resistance.
5. This product can greatly increase the filling amount of inorganic filler in resin (plastic, rubber, paint and other composite products), significantly improve the physical and mechanical properties such as tensile strength, impact strength, elongation at break, and reduce the system viscosity , Improve processing performance, reduce, energy consumption and production costs.

Examples of application effects:

The effect of HY-311, HY-311 W on the conductivity of carbon black filled soft PVC (as shown in Table 1-1)

Formula: PVC resin 100; carbon black 34; DOP 63

Titanate 0.3; Plasticizer polyester 1.7; Stabilizer 1

2. The role of coupling agent in CaCO₃filled chlorinated polyethylene (see Table 1-2)

Formula: CPE 100; DIDP 25; MgO 5; SR 5; Vulcanizing agent 5;

CaCO₃(2.5μm) 100; coupling agent 1.0

Initial properties @RT	no	KR9S	HY-311,HY-311 W
Tensile strength Psi	3010	3650	2770
Sudden change elongation%	75	110	65
Point A hardness	78	80	77
Resistance ohms/cm	220	160	75

Table 1-1

All materials are mixed by Henschel before the second roll

performance		A－172	KR39DS	KR33DS	KR238M	HY-311,HY-311 W
Initial properties of crosslinking at 177℃ for 30 minutes	300% modulus, Psi	472	636	489	449	440
q	Tensile strength, Psi	1034	909	1022	989	1011
qq	Elongation%	693	713	720	735	707
q	Sharp D-shaped hardness	29	28	29	28	28
Furnace temperature aging at 100℃ for 18hr Properties after aging	300% modulus, Psi	565	674	545	483	455
q	Tensile strength, Psi	957	944	1023	989	932
q	Elongation%	623	685	676	706	672
q	Sharp D-shaped hardness	31	31	32	29	29

Table 1-2